0.68% of solar-to-hydrogen efficiency and high photostability of organic-inorganic membrane catalyst | Nature Communications

Nature Communications volume 15, Article number: 6763 (2024) Cite this article

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Solar-driven flat-panel H2O-to-H2 conversion is an important technology for value-added solar fuel production. However, most frequently used particulate photocatalysts are hard to achieve stable photocatalysis in flat-panel reaction module due to the influence of mechanical shear force. Herein, a highly active CdS@SiO2-Pt composite with rapid CdS-to-Pt electron transfer and restrained photoexciton recombination was prepared to process into an organic-inorganic membrane by compounding with polyvinylidene fluoride (PVDF). This PVDF networked organic-inorganic membrane displays high photostability and excellent operability, achieving improved simulated sunlight-driven alkaline H2O-to-H2 conversion activity (213.48 mmol m−2 h−1) following a 0.68% of solar-to-hydrogen efficiency. No obvious variation in its appearance and micromorphology was observed even being recycled for 50-times, which considerably outperforms the existing membrane photocatalysts. Subsequently, a homemade panel H2O-to-H2 conversion system was fabricated to obtain a 0.05% of solar-to-hydrogen efficiency. In this study, we opens up a prospect for practical application of photocatalysis technology.

In recent years, solar-driven photocatalytic technology has been identified as a prospective strategy to solve the issues of environmental hazards and energy shortage1. Particularly, the photovoltaic H2O-to-H2 (HTH) conversion technique has widely attracted the research interest of many scholars in the context of carbon neutrality2. However, low photon conversion efficiency in green hydrogen production is a nonnegligible technical obstacle limiting its practical application. Therefore, a large number of high-performance photocatalysts have been developed for various applications, such as pollutant remediation3, water splitting4, CO2 reduction5, nitrogen fixation6, hydrogen peroxide production7, alkane conversion8, etc. However, most of reported photocatalysts are micro/nano-scale inorganic particulate materials, which require ultrasonic dispersion in catalytic process following a filtration or centrifugation to achieve its recovery, thus it is difficult to meet the requirement of practical applications due to the shortcomings of unstable microstructure, energy-extensive consumption, cumbersome operation, high cost, etc.

Immobilizing particulate photocatalysts on large-sized substrate (e.g., SiO2, hydrotalcite, ITO glass, polymer, etc.) can effectively improve its stability and acquire easier separation/recovery ability9,10. In view of the light dependence of photocatalyst, it has been proposed to modularize into a flat panel for indefinitely expansion, so as to realize large-scale application of photocatalytic technology11. For example, Domen’s team developed a panel reaction system based on Al-doped SrTiO3 photocatalyst for building of a 100-m2 scaled solar-to-hydrogen (STH) energy conversion system12. Subsequently, Mi et al. built a panel water-splitting system based on InGaN photocatalyst13. Generally, particulate photocatalysts were immobilized on flat-panel reaction module with the aid of adhesives (e.g., Nafion), it is easy to lose from the flat panel due to mechanical shear force influence of fluid and generated bubbles, resulting a decreased photoactivity. Moreover, single light-driven dynamics has obvious limitations for obtaining higher activity. On the one hand, it is difficult to generate higher-density photoexcitons. On the other hand, high-frequency photoexciton recombination greatly decreases photon utilization efficiency. Multi-field-driven catalysis can greatly overcome the obstacles of photocatalysis due to its merits of diversified excitation sources and faster exciton separation kinetics14.

Piezoelectric-photocatalysis is an emerging research topic developed in photocatalysis field in recent years15. For instance, Chen et al. found the piezoelectricity of 2D wrinkled WS2 monolayers by forming regions of high and low tensile strain, obtaining enhanced hydrogen production activity due to faster exciton separation16. Lan et al. utilized the synergistic effect between polarized electric field and photocarriers to obtain more efficient catalytic overall water splitting performance17. Compared with inorganic ferroelectric materials, polyvinylidene fluoride (PVDF), an organic ferroelectric material with high sensitivity of non-ultrasonic and low-frequency vibration, appears higher piezoelectric coefficient (especially the β, γ, δ phases) due to its strong polarity originated from the parallel molecular accumulation18. Moreover, in view of the merits of flexibility, chemical inertia, non-toxicity, etc., it is easy to be processed into fabric membrane structure through a simple polymer processing technique to obtain better operability19. If it is compounded with micro/nano sized inorganic photocatalysts to construct organic-inorganic composites, superior extended features (e.g., good regenerability and structural stability) can be obtained. Meanwhile, its good fluid mechanical energy sensitivity can integrate the merits of piezoelectric catalysis and photocatalysis, realizing multi-field-driven catalysis based on light energy and mechanical energy, obtaining highly improved catalytic activity.

In this work, a highly active CdS@SiO2-Pt composite with rapid CdS-to-Pt electron-transfer kinetics and restrained photoexciton recombination kinetics was prepared to process into an organic-inorganic membrane by compounding with organic ferroelectric PVDF. This PVDF networked membrane catalyst with synergistic organic-inorganic interface displays high photostability and excellent operability, dramatically overcoming the drawback of inorganic particulate catalysts, and achieving improved simulated sunlight (SSL)-driven alkaline (pH = 14.0) HTH activity with unconspicuous variation in its appearance and micromorphology after 50-times of cycles. Subsequently, a homemade panel reaction system was fabricated to drive alkaline water-splitting under SSL-irradiation. This study opens up a prospect for practical application of panel photocatalytic hydrogen production with organic-inorganic interface networked membrane technology.

SiO2 nanolayer was coated on the surface of CdS NRs to prepare the CdS@SiO2 NRs via a sol-gel method (Fig. 1a). Fourier transform infrared (FTIR) spectrum in Supplementary Fig. 1 shows strong absorption peaks assigned to the anti-symmetric stretching vibration of Si-O-Si bonds and bending vibration of Si-O bonds at 1080 cm−1 and 790 cm−1,20. Its high-resolution Si 2p and O 1s XPS spectra in Supplementary Fig. 2a, b respectively show a single characteristic peak at binding energy of 101.35 eV and two characteristic peaks at binding energies of 530.38 eV and 531.74 eV, which can be assigned to Si 2p electron orbital of SiO221 and exposed silicon hydroxyl groups and Si-O bonds22,23. Moreover, its X-ray diffraction (XRD) pattern in Fig. 1b still appear the crystal characteristic of hexagonal CdS (PDF#77-2306)24 without the observation of other crystal phases, and the typical diffraction corresponding to amorphous SiO2 is not observed around 2θ = 24°. Above results indicate that a small amount of SiO2 was successfully coated on the surface of CdS NRs, and transmission electron microscope (TEM) and high-resolution TEM (HRTEM) images in Fig. 1c provide the evidences for this conclusion. Obviously, the CdS@SiO2 composite still appears nanorod-like morphology with smooth surface and increased transverse size (Supplementary Fig. 3), and the lattice fringes of d = 0.32 nm in Supplementary Fig. 4a, b are assigned to the (101) crystal plane of hexagonal CdS25. After SiO2 coverage, a nanolayer with a thickness of ~4.86 nm can be clearly observed from the inset of Fig. 1c, forming a typical core-shell nanorod structure. As shown in Fig. 1d, compared with the bare CdS NRs (0.84 mmol g−1 h−1), a slight decrease of SSL-driven HTH rate (0.84 → 0.63 mmol g−1 h−1) is presented on CdS@SiO2 NRs, which ascribes to the inactive character of SiO2 nanolayer in HTH conversion. However, the unconspicuous photoactivity decrease indicates that the photoexcitons of internal CdS NRs can easily pass through the SiO2 nano-barrier to participate in surface reaction owing to the quantum tunneling effect of photoexcitons26,27.

a Preparation diagram of CdS@SiO2-Pt photocatalyst. b XRD patterns and (d), HTH conversion performances of CdS NRs, CdS@SiO2 NRs and CdS@SiO2-Pt photocatalysts with different Pt loading capacities (3.53%, 6.28%, 9.68%). c TEM images of CdS@SiO2 NRs. The inset of (c) is the partial magnification. Error bars in (d) indicate the standard deviation for three measurements.

Subsequently, in order to ensure the successful immobilization of Pt NPs on the surface of CdS@SiO2 NRs, its surface was amino-functionalized using 3-aminopropyl triethoxysilane (APTES). FTIR spectrum in Supplementary Fig. 1 shows obviously enhanced absorption peak assigned to the stretching vibration of N-H bonds at 3444 cm−1 20, demonstrating the successful amino-functionalization of CdS@SiO2 NRs. Then, Pt NPs was immobilized on the surface of core-shell CdS@SiO2 NRs through the complexation of amino groups and Pt4+ ions following a chemical reduction (NaBH4), and it can be clearly observed from the TEM and HRTEM images in Fig. 2a, b that a large number of well-dispersed nanoparticles with an average size of ~3 nm appear on the surface of SiO2 nanolayer. The lattice fringes (d = 0.23 nm) and diffraction spots assigned to the (111) crystal plane of face-centered cubic (fcc) phase Pt can be observed from the enlarged HRTEM image of Fig. 2c and selected area electron diffraction pattern of Fig. 2d28,29, and the nanoparticles can be further identified as Pt NPs from the energy dispersive X-ray mapping of Fig. 2e. Therefore, it proves the successful immobilization of Pt NPs on the surface of CdS@SiO2 NRs. Moreover, the loading capacity of Pt NPs on CdS@SiO2 NRs was regulated by changing the dosage of K2PtCl6, so a series of CdS@SiO2-Pt photocatalysts were prepared. The actual Pt loading capacities were determined as 3.53%, 6.28%, and 9.68% by ICP-MS technique, and the corresponding samples were represented as [email protected]%, [email protected]% and [email protected]%, respectively. Accordingly, with the increase of loading capacity of Pt NPs, the partially magnified XRD patterns in Fig. 1b appear gradually increased diffraction peak assigned to the (111) crystal plane of fcc phase Pt (PDF#87-0647) at 2θ = 39.9°30, which is consistent with the result of inductively coupled plasma mass spectrometer (ICP-MS) analysis. Figure 1d shows that loading Pt NPs on the surface of CdS@SiO2 NRs can effectively improve its SSL-driven HTH photoactivity in alkaline condition, which determines that the photoelectrons of internal CdS NRs can easily transfer to the surface Pt NPs through the SiO2 nano-barrier under photoirradiation. With the dosage increase of Pt NPs, the SSL-driven HTH rates of CdS@SiO2-Pt composite photocatalysts show a trend of first increasing and then decreasing (2.98 → 6.24 → 4.47 mmol g−1 h−1). When the loading capacity of Pt NPs is too low (e.g., [email protected]%, Supplementary Fig. 5a), the number of Pt NPs as the active sites is very small, so its ability to accept photoelectrons from internal CdS NRs is very limited, resulting low photoactivity. On the contrary, when the loading capacity of Pt NPs is too high (e.g., [email protected]%, Supplementary Fig. 5b), excess Pt NPs is easy to aggregate to form agglomerates due to the high surface energy, which significantly reduces the exposed quantity of active sites, resulting destroyed synergistic effect of cocatalyst and reducing the HTH photoactivity. Especially, the highest SSL-driven HTH rate (6.24 mmol g−1 h−1) was achieved by [email protected]% composite photocatalyst, which is about 7.4-fold greater of bare CdS NRs. Its high-resolution Pt 4 f X-ray photoelectron spectroscopy (XPS) spectrum in Supplementary Fig. 2c shows two characteristic peaks assigned to Pt 4f7/2 (69.68 eV) and Pt 4f5/2 (73.12 eV) electron orbitals of Pt0, respectively31, indicating that Pt NPs were immobilized on the surface of CdS@SiO2 NRs in zero-valence state.

a TEM images of [email protected]% composite photocatalyst. b HRTEM image, (d), SAED pattern, (e), HAADF image and EDX mappings of [email protected]% composite photocatalyst. Inset of (b) is the particle size distribution of Pt NPs on the surface of [email protected]% composite photocatalyst. c Partial magnification of (b) and corresponding line profile of selected area.

The photoelectric property play an important role in determining the catalytic performance of photocatalysts. UV-Vis absorption spectra in Supplementary Fig. 6 shows that the maximum absorption edge (λmax) of bare CdS NRs blue-shifts to 527 nm from 540 nm after coating SiO2 nanolayer, which is attributed to the non-optical response feature of SiO2 coating. Due to the quantum size of SiO2 nanolayer, the λmax of CdS@SiO2 NRs is very close to bare CdS NRs, and excellent visible-light harvesting capacity is still maintained. Further immobilizing Pt NPs on the surface, obviously red-shifted λmax is observed (527 nm→563 nm), and its absorption capacity is also enhanced significantly in broadband light range (λ > 510 nm), which is attributed to the optical enhancement of synergetic host (CdS)-guest (Pt) interaction32 and surface plasmon resonance effect of Pt NPs33,34. Therefore, the [email protected]% composite photocatalyst can be confirmed to possess excellent broadband light harvesting capacity. Furthermore, steady-state photoluminescence (PL) spectra (λex = 380 nm) in Supplementary Fig. 7 shows that coating of SiO2 nanolayer significantly reduces the PL emission intensity of bare CdS NRs, indicating effectively suppressed photoexciton recombination kinetics, which is attributed to the comprehensive influence of quantum tunneling effect of photoelectrons and nano-barrier of SiO2 coating. After anchoring Pt NPs, the PL emission intensity is further decreased significantly, which ascribes to that Pt NPs with electron-acceptor character35,36 can rapidly accept photoelectrons tunneling from the internal CdS NRs through SiO2 nanolayer due to lower potential energy, thus greatly suppressing the photoexciton recombination kinetic, and acquiring higher photon utilization efficiency.

All electrochemical data were tested on a light-assisted three-electrode system (Fig. 3a). Light-induced electrochemical impedance spectroscopies (EIS) in Supplementary Fig. 8 show slightly increased interfacial impedance of CdS NRs due to the coating of SiO2 nanolayer, but it further decreases significantly with immobilization of Pt NPs. This result powerfully proves that photoexcitons in [email protected]% composite photocatalyst can easily cross SiO2 nanolayer from internal CdS NRs to the surface Pt active sites due to its quantum tunneling effect. Furthermore, transient photocurrent-time curves in Supplementary Fig. 9 display the intensity trend of CdS@SiO2 < CdS <[email protected]%, which is basically consistent with the results of UV-Vis absorption spectra and EIS analysis. On the one hand, the SiO2 nanolayer does not significantly affect the photoexciton separation kinetics of CdS NRs under photoirradiation. On the other hand, the electron donor (CdS)-electron acceptor (Pt) interaction greatly promotes the photoelectron migration from internal CdS NRs to surface Pt active sites through the SiO2 nano-barrier, making the catalyst surface a main area for enriching photoelectrons37. In fact, it can be found from the light-induced linear sweep voltammetry curves of Supplementary Fig. 10 and Tafel polarization curves of Supplementary Fig. 11 that the [email protected]% composite photocatalyst shows lower onset potential (0.91 V vs. −2 mA cm−2) and smaller polarized overpotential (917 mV) for photoelectrochemical hydrogen evolution compared with CdS NRs and CdS@SiO2 NRs, which provides the powerful evidences for the faster HTH kinetics24.

a Schematic diagram of the three-electrode electrochemical test system, light density (99.1 mW·cm−2) of the irradiated light source and the working electrodes of inorganic catalyst and membrane catalyst. b 2D mapped TA spectra, (c), TA spectra, (d), attenuated TA spectra of [email protected]% composite photocatalyst. e, f Decay kinetic curves of CdS NRs and [email protected]% composite photocatalyst. g Band structure of [email protected]% composite photocatalyst. The fs-TA tests were performed under excitation of a 380 nm-pump pulse.

Femtosecond transient absorption (fs-TA) spectroscopy technique was adopted under excitation of a 380 nm-pump pulse to investigate the exciton dynamics of the optimal [email protected]% composite photocatalyst. The two-dimensional (2D) mapped TA spectra of CdS NRs and [email protected]% composite photocatalyst display obvious excited state absorption (ESA) signal at 457 nm (Supplementary Fig. 12a and Fig. 3b), which ascribes to the generation of hot excitons in CdS NRs after excitation38. Compared with CdS NRs, the [email protected]% composite photocatalyst shows a slightly blue-shifted ground state bleaching (GSB) signal (516 nm→513 nm), indicating that it is easier to reach the excited state under the same excitation39, which is attributed to the synergistic host (CdS NRs)-guest (Pt NPs) electronic interaction. Supplementary Fig. 12b, c and Fig. 3c, d are the TA spectra of CdS NRs and [email protected]% composite photocatalyst at different relaxation times. It is obvious that the TA intensity of GSB peak increases rapidly in fs range (500 fs) after photoexcitation, and it decreases gradually in subsequent picosecond (ps) and nanosecond (ns) ranges, which ascribes to the instantaneous generation and subsequent recombination of excitons40. Comparatively, the maximum TA intensity of [email protected]% composite photocatalyst is stronger than that of bare CdS NRs, indicating that more hot excitons are generated under same excitation40. Furthermore, a new GSB signal (~740 nm) can be observed from the TA spectra in relaxation time range of 1−200 ps (Fig. 3c), corresponding to its 2D mapped TA spectrum, which is attributed to the CdS NRs-to-Pt NPs hot electron transfer through SiO2 nanolayer41. Moreover, compared with bare CdS NRs (Fig. 3e), two fast decay processes (τ1 = 14.43 ps, τ2 = 110.02 ps) can be observed in the fitted decay kinetics curve of [email protected]% composite photocatalyst (Fig. 3f). The former is attributed to the CdS NRs-to-Pt NPs electron transfer through SiO2 nanolayer, while the latter indicates the faster conduction band (CB)-to-trapping state (TS) electron transfer of [email protected]% composite photocatalyst than CdS NRs. This can be attributed to that the electron-acceptor feature of Pt NPs enables it to quickly accept tunneling electrons from CdS NRs, providing a strong driving force for accelerating exciton transfer42. Moreover, [email protected]% composite photocatalyst (τ3 = 1348.71 ps) has a longer hot exciton decay lifetime than bare CdS NRs (τ2 = 288.33 ps), demonstrating that the rapid CdS NRs-to-Pt NPs charge transfer ability greatly restrains the photoexciton recombination kinetics43.

The flat-band potential of CdS NRs can be determined as Efb(Ag/AgCl) = −1.31 V according to its Mott-Schottky curves at different frequencies (Supplementary Fig. 13), and it can be further converted to −0.70 V vs. reversible hydrogen electrode (RHE) potential by following our previous method24. Since all the linear parts of Mott-Schottky curves show a positive slope, the ECB of CdS NRs can be determined as ECB(RHE) = -0.90 V due to the n-type semiconductor characteristic. Furthermore, its bandgap can be determined as Eg = 2.37 eV from the (ahν)n/2 ~ hν pattern in Supplementary Fig. 14, thereby its valence band position can be confirmed to be EVB(RHE) = 1.47 V. The specific calculation formulas are given in Supplementary Information. Due to the lower chemical potential of surface Pt NPs, the band structure of [email protected]% composite photocatalyst can be proposed as Fig. 3g.

In order to overcome the drawback of particulate photocatalyst in actual application, the optimal inorganic photocatalyst was compounded with organic ferroelectric PDVF to process into organic-inorganic membrane via a electrospinning technique (Fig. 4a, b). Scanning electron microscope (SEM) images in Fig. 4c show that this membrane is composed by abundant fibers exposing a large number of inorganic materials (Fig. 4d), which benefits to the expose of active sites. As shown in Fig. 4e, pure PVDF membrane can not drive HTH conversion under SSL-irradiation, while all PVDF/CSP membrane catalysts show prominent SSL-driven HTH photoactivity. Moreover, the expose of inorganic catalyst can be well regulated by adjusting its dosage (Supplementary Fig. 15a–f), so as to further control the number of active sites on organic-inorganic matrix. However, it is obvious that excessive inorganic catalyst leads to the aggregation in organic matrix (Supplementary Fig. 15f) due to the uneven dispersion, which will break the synergistic interaction of organic-inorganic interface. Therefore, with the dosage increase of inorganic catalyst, the photoactivities of membrane catalysts showed a trend of increasing first and then decreasing (Fig. 4e). Especially, when the dosage of inorganic catalyst was 0.14 g, the membrane catalyst (PVDF/CSP0.14) achieved the highest HTH rate (160.98 mmol m−2 h−1), and it further reached to 213.48 mmol m−2 h−1 and acquired 0.68% of STH efficiency by regulating the thickness of membrane catalyst (Fig. 4f), which considerably outperforms the existing membrane photocatalysts (Table 1)44,45,46,47,48,49.

a Digital photo of electrospinning equipment. b Schematic diagram of electrospinning technique. c SEM image and (d), EDS mappings of PVDF/CSP0.14 membrane catalyst. e HTH performances of membrane catalysts with different dosage of inorganic catalyst (0 g → 0.16 g) and (f), different thickness (50 μm → 190 μm). g Cyclic HTH performances of PVDF/CSP0.14 membrane catalyst. h Digital photos and SEM images of fresh and recovered PVDF/CSP0.14 membrane catalyst. Inset of (a) is the digital photo of PVDF/CSP0.14 membrane catalyst with the size of 21 cm × 24 cm. Inset of (c) is the partial magnification. Inset of (e) is the light density (212.9 mW·cm-2) used in HTH performance evaluation. Error bars in (e, f) indicate the standard deviation for three measurements.

The micro-structural variation and mass loss of particulate catalyst in cyclic process inevitably affect its photoactivity50,51. Satisfyingly, the PVDF networked membrane catalyst (PVDF/CSP0.14) with synergistic organic-inorganic interface maintained a highly stable photoactivity in 50 cycles (Fig. 4g) due to its high structural stability and convenient separation/recovery property. Owing to the limitation of experimental period (hundreds of hours), the photoactivity may still maintain satisfactory stability even continuously increasing the cyclic number. In addition, the photocurrent response remained stable under long-term (5 h) photoirradiation (Supplementary Fig. 16), which also fully illustrates the excellent light stability and well supports the claim of maintaining highly stable photoactivity over 50 cycles. FTIR spectra in Supplementary Fig. 17 shows that the recovered PVDF/CSP0.14 membrane catalyst still display obvious α, β and γ phase characteristics assigned to ferroelectric PVDF52 even being reused dozens of times, and the digital photos and SEM images in Fig. 4h also did not appear obvious variation in the appearance and micromorphology after 50-times of cycles, suggesting the strong regenerability. Therefore, it indicates that the drawback of particulate catalyst in long-term photo-activation was dramatically overcome to better meet practical application. Stress-strain curves in Supplementary Fig. 18 indicate that the compound of inorganic particulate catalyst significantly increase the tensile strength (3.34 MPa→4.11 MPa) and tensile elongation yield (0.65% → 0.88%) of PVDF membrane, suggesting significantly enhanced mechanical strength. Meanwhile, the PVDF/CSP0.14 membrane catalyst possesses smaller interfacial impedance than pure PVDF membrane (Supplementary Fig. 19), indicating that the formation of synergistic organic-inorganic interface significantly promotes exciton transfer. Based on the superior broadband light harvesting capacity of inorganic catalyst and piezoelectric effect of PVDF matrix, the PVDF/CSP0.14 membrane catalyst appears stronger response current signals under transient induction of photoirradiation (Supplementary Fig. 20) or ultrasound (Supplementary Fig. 21) than pure PVDF membrane, suggesting the potential of photo-activation and piezoelectric activation. The strong piezoelectric current and voltage signals in Supplementary Fig. 22a, b and the obvious performance advantage of PVDF/CSP0.14 membrane catalyst than the non-ferroelectric composite membrane (polyurethane (PU)/VSP0.14) in Supplementary Fig. 23 provide the direct evidences to this conclusion.

Subsequently, a homemade panel water-splitting reaction system was fabricated as Fig. 5a Alkaline water (pH = 14.0) flowed into the panel reaction module embedded membrane catalyst (16 cm × 23 cm) at a flow rate of 20 mL/min under driving of peristaltic pump. When the panel reaction module is filled, it was irradiated by a xenon lamp to drive water splitting. Water-gas mixture flowed into a gas-liquid separation bottle from panel reaction module, and gaseous product was dried in a drying bottle containing concentrated sulfuric acid and subsequently entered a gas collecting bottle as Fig. 5b. As shown as the inset of Fig. 5a and supplemented Supplementary Movie 1, it can be observed from the panel reaction module that a large number of bubbles are continuously evolved on the surface of membrane catalyst under SSL-irradiation. With continuous reaction, bubbles were released in drying bottle (Fig. 5c), and supplemented Supplementary Movie 2 provides direct evidence for this phenomenon. After 3 h of reaction, gas sample was extracted from the sampling port of gas collecting bottle for gas chromatographic detection, and chromatographic peaks belonging to hydrogen and oxygen appeared as Fig. 5d, e, indicating the successful progress of water splitting process in this panel reaction system. The ignition experiment of collected gas in inset of Fig. 5e and Supplementary Movie 3 further provides the evidence for this conclusion, and 0.05% of STH efficiency was achieved on this panel reaction system for water splitting. Due to the high stability of this membrane catalyst, no active catalyst lost from the panel reaction module even suffering long-term mechanical forces of fluid flow and bubble collision. By increasing the number of panel modules, the scale of panel reaction system can be expanded as Supplementary Fig. 24, so that water splitting can be achieved under strong outdoor solar-irradiation. Of course, there are still many engineering problems to be solved in actual operation. Based on our study, the catalytic mechanism of this membrane catalyst for HTH conversion is proposed as Supplementary Fig. 25. Owing to the excellent broadband light-harvesting capacity of inorganic catalyst and sensitive piezoelectricity of PVDF matrix, the membrane catalyst in panel reaction module can be double-activated under stimulations of light energy and mechanical energy, thus generating high-density excitons (e− + h+) to drive HTH conversion (1). Due to the presence of hydroxyl groups on the surface of SiO2 nanolayer and the influence of a large number of OH− ions in aqueous phase, a low chemical potential conducive to the transfer of photogenerated h+ from CdS NRs to the surface of SiO2 nanolayer is formed, and related oxidation reactions can be achieved on the surface of the catalytic material, effectively avoiding the impact of corrosion on the internal CdS microstructure. The relevant processes are shown as follows: (1)~(4). In this catalytic process, OH− ions consume most of the photogenerated h+ (4), thus better promoting the half-reaction of hydrogen production (3).

a Digital photos of laboratorial panel reaction system based on the membrane catalyst: b gas collecting bottle and (c), bubble display in gas drying bottle. d Hydrogen standard curve obtained on a gas chromatograph (FULI, GC 9790II, CN). e Gas chromatogram of gaseous product from this panel reaction system.

In summary, in order to overcome the drawback of particulate photocatalysts in flat-panel HTH conversion, a highly active CdS@SiO2-Pt composite with rapid CdS-to-Pt electron-transfer kinetics and restrained photoexciton recombination kinetics was prepared to process into an organic-inorganic membrane by compounding with organic ferroelectric PVDF. This PVDF networked membrane catalyst with synergistic organic-inorganic interface displays high photostability and excellent operability, achieving improved SSL-driven alkaline (pH = 14.0) HTH activity (213.48 mmol m−2 h−1) following a 0.68% of STH efficiency. No obvious variation in its appearance and micromorphology was observed even being recycled for 50-times, which considerably outperforms the existing membrane photocatalysts. Subsequently, a homemade panel reaction system was fabricated to achieve alkaline water-splitting to obtain a 0.05% of STH efficiency under SSL-irradiation. This study opens up a prospect for practical application of panel photocatalytic hydrogen production with organic-inorganic interface networked membrane technology.

All chemical reagents used in this study were purchased from Sinopharm Group Chemical Reagents Co., LTD without any purification treatment.

The CdS NRs were hydrothermally synthesized by following our previous protocol25, and the detailed procedure is given in Supplementary Information. The CdS@SiO2 NRs were prepared by coating a SiO2 nanolayer on the surface of CdS NRs via a sol-gel method (Fig. 1a). Specifically, 0.3 g CdS NRs was ultrasonically dispersed in a mixed solution of 20 mL deionized water and 40 mL absolute ethanol (A.R.), and the dispersion was magnetically agitated for 15 min after adding 1 mL NH3 · H2O (25 wt%). Then, 2 mL tetraethoxysilane (TEOS, A.R.) was added to this mixture drop by drop following a 6 h of magnetic agitation at room temperature. After the reaction, the product was centrifuged and rinsed for several times with deionized water, and powdered CdS@SiO2 NRs was obtained after heat drying at 80 °C.

Amino-functionalization of core-shell CdS@SiO2 NRs was achieved through the bonding interaction between silane coupling agent and silicon hydroxyl group. 1 g CdS@SiO2 NRs was ultrasonically dispersed in 50 mL acetone (A.R.), and 1 mL APTES (A.R.) and 2 drops of NH3 · H2O (25 wt%) were added to this dispersion following a 3 h of magnetic agitation at 50 °C under reflux condensation. After the reaction, the sample was centrifuged and rinsed for several times with ethanol and deionized water, and amino-functionalized CdS@SiO2 NRs (CdS@SiO2-NH2) was obtained after heat drying at 80 °C.

The Pt NPs was immobilized on the surface of core-shell CdS@SiO2 NRs through the complexation of surface amino groups and Pt4+ ions following a reduction process (Fig. 1a). 0.1 g as-prepared CdS@SiO2-NH2 and 0.01 g K2PtCl6 (A.R.) were added to 25 mL deionized water for 30 min of magnetic agitation, and 10 mL deionized water dissolving appropriate amount of NaBH4 (A.R.) was added to this mixture by drops. After 2 h of continuous agitation, the sample was collected and rinsed for several times with deionized water, and CdS@SiO2-Pt composite photocatalyst was obtained after heat drying at 80 °C. In this process, the amount of Pt NPs in composite can be precisely regulated by adjusting the dosage of K2PtCl6, thus to prepare a series of CdS@SiO2-Pt composite photocatalysts with different Pt dosages. The actual Pt loading capacities were determined on an inductively coupled plasma mass spectrometer (ICP-MS, ICPA 6000 SERIES, USA).

The PVDF/CSP membrane catalyst was processed via an electrospinning technique by compounding the optimal inorganic photocatalyst with PVDF. Concretely, 0.5 g PVDF powder (\(\bar{M}\) = 500 thousands) was dissolved in a mixed solvent of 3.36 mL DMF (A.R.) and 2.24 mL acetone (A.R.), and a certain amount of inorganic photocatalyst was ultrasonically dispersed in this polymer solution. The precursor mixture for electrospinning was prepared after 30 min of agitation at 40 °C, and the uniform mixture was transferred to a syringe with a volume of 10 mL and sprayed at a steady flow rate of 1 mL h−1 and a potential of 9.32 kV through a 0.6 mm needle. The rotating speed of collecting drum was 200 rpm, which is 15 cm from the needle, and the moving speed of sliding platform was 32 mm s−1. After 4 h of spinning and 2 h of heat drying at 60 °C, the PVDF/CSP membrane catalyst with a size of 21 cm × 24 cm was obtained. In this process, a series of membrane catalysts were processed by adjusting the amount of inorganic photocatalyst, and the resultant materials were expressed as PVDF/CSPα (Here, α represents the mass of inorganic photocatalyst in membrane catalyst). Meanwhile, the bare PVDF membrane was prepared for contrast by the same procedure at absence of inorganic photocatalyst. In addition, the PVDF powder was replaced by PU powder to process the PU/CSP membrane catalyst for contrast by the same operation.

The crystal structures of the samples were analyzed on a powder X-ray diffractometer (XRD, D8 Advance, GER). Fourier transform infrared spectrometer (FTIR, Bruker Alpha VECTOR 22, GER) and X-ray photoelectron spectrometer (XPS, AXIS SUPRA, UK) were performed to analyze the chemical structure, elemental composition and chemical states of the samples. The topology and crystallography of the samples were observed on a field emission transmission electron microscope (TEM, FEI Tecnai G2 F30 S-TWIN, USA) and field emission scanning electron microscopy (SEM, SU8100, Japan). UV-Vis absorption spectra were measured on a UV-Vis-NIR spectrophotometer (Agilent, Cary 5000, USA), and steady-state photoluminescence (PL) spectra were measured on a fluorescence spectrometer (Edinburgh FLS980, UK), and the excitation wavelength (λex) and emission wavelength (λem) was set as 380 nm and 544 nm, respectively. Femtosecond transient absorption (fs-TA) spectroscopy was performed to investigate the exciton dynamics utilizing a coherent legend laser system equipped a home-modified Helios (ultrafast) device. This measurement involved in an 800 nm of laser (2840 mW) emitting from a seed source through a titanium sapphire amplifier, and the pulse frequency and time interval are 1000 Hz and 75 fs, respectively.

The HTH photoactivity was evaluated on a Labsolar-III AG system of Beijing Perfectlight Technology Co., Ltd. equipped with a 300 W xenon lamp (MC-PF300C, 212.9 mW·cm−2) and a gas chromatograph (FULI, GC 9790II, CN) by using high purity nitrogen as carrier gas. All error bars were determined according to three measurements.

For inorganic photocatalysts, 50 mL deionized water uniformly dispersing 10 mg catalyst was added to a closed glass photoreactor after regulating the pH value to 14.0 with 0.1 M NaOH solution. After 10 min of degassing treatment, it was photoirradiated for 4 h under magnetic agitation, and sampling and detecting were performed every 1 h to determine the amount of hydrogen by comparing with its standard curve in Supplementary Fig. 26.

For membrane catalysts, a circular membrane catalyst with a diameter of 6.5 cm was cut to replace the inorganic particulate photocatalyst and fixed in the closed glass photoreactor to perform the HTH conversion, and the membrane catalyst was impregnated 0.3 cm below the liquid level in photocatalytic process. After the reaction, the membrane was collected and rinsed several times with deionized water to achieve its regeneration for next reuse. All cyclic experiments were performed using the same operation.

The STH efficiency of the optimal membrane catalyst for SSL-driven alkaline HTH conversion was calculated using the method reported in literature49,53, and the specific calculation method is as follows:

where \({R}_{{H}_{2}}\) represents the HTH rate (1.99 × 10−7 mol·s−1), \(\triangle {G}^{0}\) represents its standard Gibbs free energy (237.13 × 103 J mol−1 at 298 K), P represents the light intensity of irradiated light (212.9 mW cm−2), and S represents the illuminated area (33.17 cm2).

All photoelectric data was detected on an electrochemical workstation (CHI 660E, CN) equipped a 350 W xenon lamp (BBZM-III, CN, 99.1 mW cm−2, Fig. 3a), and a three-electrode system composed of working electrode, counter electrode (Pt electrode) and reference electrode (Ag+/AgCl electrode) was installed in a quartz groove containing 0.2 M Na2SO4 electrolyte (pH = 7). For inorganic catalysts, ITO glasses (15 mm × 15 mm) coated by tested samples were used as the working electrodes54. Detailedly, 5 mg tested sample was ultrasonically dispersed into the mixed solution of 3 mL anhydrous ethanol and a drop of naphthol to form a uniform mixture, and it was uniformly coated on the conductive side of the ITO glass through a pipette following a drying treatment in an oven (60 °C). Repeating the above coating and drying operations until the mixed liquid is exhausted completely. For membrane catalysts, 15 mm × 15 mm of square membranes were cut and bonded to a conductive copper adhesive with the same size to get the working electrode for test of photoelectric properties. The specific test parameters were same as that of inorganic catalysts and is provided in Supplementary Information.

The synthesis of CdS NRs, parameters for photoelectric property tests, Kubelka-Munk function, calculation formulas for band structure and the supplemented data are contained in Supplemented Information.

Further information on research design is available in the Nature Portfolio Reporting Summary linked to this article.

Source data are provided as a Source Data file. Source data are provided with this paper.

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The authors are grateful for the financial supports of the National Natural Science Foundation of China (22376131, 52161145409 & 21976116). Special thanks to Prof. Kazunari Domen for his constructive comments on this manuscript, which greatly help improve this paper.

College of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Additives for Industry, Shaanxi University of Science and Technology, Xi’an, Shaanxi, China

Wei Li, Wen Duan, Guocheng Liao, Fanfan Gao, Yusen Wang & Rongxia Cui

Key Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, PR China

Jincai Zhao

School of Environmental Sciences and Engineering, Shaanxi University of Science and Technology, Xi’an, Shaanxi, China

Chuanyi Wang

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W. Li proposed the experimental concepts, designed the experiments and prepared the paper. W. Li and C. Wang supervised the project. W. Li, W. Duan, G. Liao, F. Gao, Y. Wang, and R. Cui carried out the experiments and conducted the materials characterization. W. Li, C. Wang, and J. Zhao revised the paper. All authors discussed the results and approved the final version of the paper.

Correspondence to Wei Li or Chuanyi Wang.

The authors declare no competing interests.

Nature Communications thanks the anonymous reviewers for their contribution to the peer review of this work. A peer review file is available.

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Li, W., Duan, W., Liao, G. et al. 0.68% of solar-to-hydrogen efficiency and high photostability of organic-inorganic membrane catalyst. Nat Commun 15, 6763 (2024). https://doi.org/10.1038/s41467-024-51183-2

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Received: 18 February 2024

Accepted: 31 July 2024

Published: 08 August 2024

DOI: https://doi.org/10.1038/s41467-024-51183-2

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